期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 12, 页码 6083-6092出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00540
关键词
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资金
- National Natural Science Foundation of China [21302110, 21302109, 21375075]
- Taishan Scholar Foundation of Shandong Province
- Project of Shandong Province Higher Educational Science and Technology Program [J13LD14]
- Natural Science Foundation of Shandong Province [ZR2013BQ017]
Iodine-catalyzed direct arylthiation of substituted anilines for the synthesis of various diaryl sulfides has been developed under metal- and solvent-free conditions. The present method uses readily available thiols as the arylthiation reagents, and environmentally friendly and inexpensive I-2 as the catalyst. Importantly, no base or ligand was necessary. Such a simple, efficient, and economical transformation provides an attractive approach to various diaryl sulfides in good to excellent yields.
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