期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 24, 页码 12659-12667出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02251
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资金
- CSIR, India
- IIT-Kanpur
- DST, India
A simple strategy for the syntheses of 2-alkyl indoles via regioselective ring-opening of 2-(2-haloaryl)-3-alkyl-N-tosylaziridines with thiophenol, followed by copper powder-mediated intramolecular C-N cyclization and subsequent aromatization by the elimination of thiophenol, with good yields is described. Utilizing this protocol, 2-carboxyindole has been synthesized easily.
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