期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 5, 页码 2503-2512出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00065
关键词
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资金
- National Natural Science Foundation of China [21172081, 21372090]
- Natural Science Foundation of Guangdong Province [S2013020013091]
- Education Department of Guangdong Province [2011A090200039]
- city of Guangzhou science and technology plan projects [156300018]
- Guangzhou Pearl River New Star Plan of Science and Technology Program [2012J2200015]
A platinum(II)-catalyzed asymmetric ring opening of oxabenzonorbornadienes with phenols was developed, which afforded the corresponding cis-2-(un)substituted phenoxy-1,2-dihydronaphthalen-1-ol products rather than the trans ones in excellent yields (up to 99%) with moderate to good enantioselectivities (up to 87% ee) under mild conditions. In addition, the cis-configuration of product 2b was confirmed by X-ray diffraction analysis. Based on the results, a potential mechanism for the present catalytic reaction was proposed.
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