期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 4, 页码 2397-2406出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo502602u
关键词
-
资金
- University of California
- UC San Diego Hellman Fellowship Program
- NSF [CHE-0741968, CHE-9709183]
The mulinane class of diterpenoids is a set of tricyclic (5-6-7), biologically active natural products whose members exhibit a variety of oxidation states. Herein, we report the inaugural synthesis of four mulinanes employing a divergent approach that relies on a diastereoselective anionic oxy-Cope rearrangement to set the relative configuration of the C8 stereocenter and an unprecedented vinylogous Saegusa dehydrogenation reaction to address C-ring functionality.
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