期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 81, 期 2, 页码 553-558出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02395
关键词
-
资金
- NSERC [2014-04410]
The use of a bis(diisopropylamino)cyclopropenimine-substituted bis-protonated proton sponge as a bifunctional phase-transfer catalyst is reported. Experimental studies and DFT calculations suggest it operates simultaneously as a hydrogen bond donor and a phase-transfer catalyst, facilitating the movement of charged intermediates from the interface to the organic phase via favorable partitioning of hydrophilic/hydrophobic surface areas, resulting in high catalytic activity.
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