期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 13, 页码 6846-6855出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b00477
关键词
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资金
- UGC, New Delhi
- DST, Government of India [SR/S1/OC-13/2011]
Synthesis of indolizine-1-carboxylates through the Ortoleva-King reaction of 2-pyridylacetate followed by the Aldol condensation under mild reaction conditions has been described. This protocol is compatible with a broad range of functional groups, and it has been also successfully extended to unsaturated ketones, bringing about the regioselective formation of benzoyl-substituted indolizines through Michael addition followed by C-N bond formation, which are difficult to prepare by previous methods in a single step.
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