期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 15, 页码 7547-7554出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01126
关键词
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资金
- 973 project from the MOST of China [2015CB856600]
- NSFC [21272221, 21472179]
- Recruitment Program of Global Experts
- Fundamental Research Funds for the Central Universities [WK 2060190028, 2060190026, 3430000001]
- Fundamental Research Funds for Central Universities
- Cross-disciplinary Collaborative Teams Program for Science, Technology and Innovation from Chinese Academy of Sciences
A palladium-catalyzed domino cyclization and carboxylation reaction for synthesis of a variety of carboxylic acids was developed, where chloroform was used as carbon monoxide source. The in situ generated neopentylpalladium species by Heck cyclization was efficiently trapped by dichlorocarbene to form a series of carboxylic acids. It was found that in this type of domino reaction CHCl3 is a convenient and safe alternation for CO gas.
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