期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 21, 页码 11138-11142出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01869
关键词
-
资金
- National Natural Sciences Foundation of China [21172031, 21372040]
- National Natural Science Foundation of Jilin [20140101113JC]
Starting from beta-oxodithioesters and hydroxylamine, two completely different transformations afford either beta-ketonitriles or isoxazoles with high chemoselectivity depending on the reaction conditions. The reaction of beta-oxodithioesters with hydroxylamine in EtOH at room temperature in daylight gave beta-ketonitriles in high yields. On the other hand, 3-methylthio-isoxazoles were efficiently obtained as the final products by heating the mixture of beta-oxodithioesters and hydroxylamine in HOAc at 90 degrees C.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据