期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 24, 页码 12027-12037出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01956
关键词
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资金
- FAPESP [09/51602-5, 13/07607-8]
- CNPq [131015/2014-1]
- Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [09/51602-5, 13/07607-8] Funding Source: FAPESP
A successful combination of computational chemistry and total synthesis was explored to tentatively elucidate the absolute configuration of cryptomoscatone E3, a polyketide isolated from the Brazilian tree Cryptocarya mandiocanna. Two independent synthetic approaches are discussed based on asymmetric allylation, ring closing metathesis, and aldol reactions.
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