期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 16, 页码 8096-8101出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01194
关键词
-
资金
- National Natural Science Foundation of China [21072067]
New chiral tetraphenylethylene (TPE) macrocycles bearing optically pure amine groups were synthesized and found to have a discriminating ability between the two enantiomers of not only chiral acidic compounds but also alpha-amino acids by enantioselective aggregation and aggregation-induced emission (ATE) effects. NMR spectra, including 2D-NOESY, disclosed that the host-guest interaction of the macrocyde receptor played a key role in addition to the acid-base interactions.
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