期刊
DESALINATION
卷 265, 期 1-3, 页码 81-87出版社
ELSEVIER
DOI: 10.1016/j.desal.2010.07.035
关键词
Anionic dye; Adsorption; Modified hectorite; Kinetics; Thermodynamics
资金
- Natural Science Foundation of China [20976184]
- Science and Technology Brainstorm Project of Qinghai Province [2007-G-112]
Two modified hectorites have been designed and synthesized by two cationic surfactants namely cetyltrimethyl ammonium bromide (CTAB) and octadecylamine (ODA) for selective removal of the anionic dye congo red (CR) from aqueous solution. The adsorbent capacity of modified hectorites was discussed and the optical contents of CTAB and ODA were 35% and 28%, respectively. Modified hectorites were characterized by X-ray powder diffractometer (XRD), Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). The effects of adsorbents content and adsorption temperature on the sorption of CR on modified hectorites were studied. Experimental results showed that the equilibrium adsorption data fitted well with the Langmuir isotherm and the adsorption capacities were 182 and 197 mg/g for the modified cetyltrimethyl ammonium bromide hectorite (CTAB-Hect) and ammonium bromide hectorite (ODA-Hect), respectively. Kinetic studies showed that the dynamical data fitted well with the pseudo-second-order kinetic model. For thermodynamic studies, parameters such as the Gibbs free energy (Delta G(0)), the enthalpy (Delta H-0) and the entropy (Delta S-0) indicated that the adsorption process was spontaneous and endothermic in nature. (C) 2010 Elsevier B.V. All rights reserved.
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