期刊
DESALINATION
卷 268, 期 1-3, 页码 90-96出版社
ELSEVIER
DOI: 10.1016/j.desal.2010.10.002
关键词
Sorption; Thermal analysis; Morphology; Ion-exchange resins; Activation energy
A new chelating terpolymer resin was synthesized from 8-hydroxyquinoline and salicylic acid with formaldehyde (QSF) by solution condensation technique in acid medium. The terpolymer resin was characterized by elemental analysis, infra-red and nuclear magnetic resonance (H-1 and C-13 NMR) spectroscopy. The structure of the terpolymer was confirmed on the basis of spectral data. The thermogravimetric analysis (TGA) was performed to evaluate the thermal degradation characteristics and also to calculate the kinetic parameters such as activation energy and the order of the reaction. The average molecular weight and the polydispersity index for the terpolymer were calculated by gel permeation chromatography (GPC). The surface characteristics were examined through scanning electron microscopy (SEM) at different magnifications. A batch equilibrium method was employed to study the selectivity and sorption capacity of the terpolymer resin towards certain divalent metal ions such as Pb2+, Zn2+, Cu2+, Ni2+, Ba2+, Co2+ and Mn2+ in various electrolyte concentrations, wide pH ranges and different time intervals. From the ion-exchange studies, the QSF terpolymer was found to be an excellent cation exchanger for selective metal ions. (C) 2010 Elsevier B.V. All rights reserved.
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