期刊
DALTON TRANSACTIONS
卷 47, 期 41, 页码 14452-14461出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8dt02658k
关键词
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资金
- Heavy Element Chemistry Program at LANL by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy
- U.S. Department of Energy
- National Nuclear Security Administration of U.S. Department of Energy [DE-AC52-06NA25396]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Heavy Elements Chemistry Program [DE-FG02-13ER16414]
- U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES) [DE-SC0016568]
- Glenn T. Seaborg Institute
- LDRD office
- U.S. Department of Energy (DOE) [DE-SC0016568] Funding Source: U.S. Department of Energy (DOE)
Characterizing how actinide properties change across the f-element series is critical for improving predictive capabilities and solving many nuclear problems facing our society. Unfortunately, it is difficult to make direct comparisons across the 5f-element series because so little is known about trans-plutonium elements. Results described herein help to address this issue through isolation of An(S2CNEt2)(3)(N2C12H8) (Am, Cm, and Cf). These findings included the first single crystal X-ray diffraction measurements of Cm-S (mean of 2.86 +/- 0.04 angstrom) and Cf-S (mean of 2.84 +/- 0.04 angstrom) bond distances. Furthermore, they highlight the potential of An(S2CNEt2)(3)(N2C12H8) for providing a test bed for comparative analyses of actinide versus lanthanide bonding interactions.
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