期刊
DALTON TRANSACTIONS
卷 43, 期 48, 页码 17885-17888出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4dt01636j
关键词
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资金
- National Science Foundation [CHE-1149875]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1149875] Funding Source: National Science Foundation
The first uranium(III) charge separated ketyl radical complex, Tp*U-2(OC center dot Ph-2), has been isolated and characterized by infrared, H-1 NMR, and electronic absorption spectroscopies, along with X-ray crystallography. Tp*U-2(OC center dot Ph-2) is a potent two-electron reductant towards N(3)Mes (Mes = 2,4,6-trimethylphenyl) and (2,2,6,6-tetramethyl-piperidin-1-yl) oxyl (TEMPO), with reducing equivalents derived from the metal centre and the redox-active benzophenone.
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