期刊
DALTON TRANSACTIONS
卷 43, 期 13, 页码 5054-5061出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt52872c
关键词
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资金
- Generalitat de Catalunya [2009/SGR/00279]
- Ministerio de Ciencia e Innovacion [CTQ2010-16237]
- MEC for a FPU predoctoral grant [AP2007-01723]
- European Community Seventh Framework Programme [263878]
- CONACYT [125141]
The preparation of 3-4 nm and 10 nm gold nanoparticles capped with neutral carborane-based mercaptocarboranes, via two different preparative routes, is reported. The resulting boron-enriched nanomaterials exhibit complete dispersibility in water, opening the way for the use of these monolayer protected clusters (MPCs) in medical applications, such as boron neutron capture therapy (BNCT). These newly prepared MPCs have been characterized by FTIR, H-1 and B-11 NMR spectroscopy, UV-visible, centrifugal particle sizing (CPS), and, in some cases, inductively coupled plasma atomic emission spectrometry (ICP-AES). Water dispersibility exhibited by these MPCs allowed the study of the cellular uptake by HeLa cells.
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