期刊
DALTON TRANSACTIONS
卷 43, 期 2, 页码 632-638出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt52373j
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资金
- NRW Research School (Graduate School of Chemistry, University Munster)
- European Research Council (ERC)
Two (aryl)PXY starting materials (aryl = mesityl or 2,4,6-triisopropylphenyl; X,Y = Cl, Br) were reacted with lithiated conjugated enynes (derived from 2-methylbutenyne or 1-ethynylcyclohexene) to yield the respective (aryl)bis(enynyl)phosphanes. Their reaction with HB(C6F5)(2) gave the heterocyclic five-membered zwitterionic borata-diene compounds containing the aryl group and one unchanged enynyl substituent at phosphorus. The borata-alkene products were thought to arise from a two step process of regioselective alkyne hydroboration followed by an internal phosphane attack on the boryldiene unit. Three examples of the ring-closed borata-alkene type products were characterized by X-ray diffraction.
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