期刊
DALTON TRANSACTIONS
卷 42, 期 15, 页码 5224-5227出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt50255d
关键词
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资金
- Royal Society
- EPSRC
- ERC
- University of Nottingham, COST Action [CM1006]
- UK National Nuclear Laboratory
- EPSRC [EP/K038869/1, EP/G051763/1, EP/K024000/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G051763/1, EP/K024000/1, EP/K038869/1] Funding Source: researchfish
Reduction of [U(Ts-Tol)(Cl)(mu-Cl)U(Ts-Tol)(THF)(2)] [2, Ts-Tol = HC-(SiMe2NAr')(3); Ar' = 4-MeC6H4)] with KC8 in toluene afforded the new arene-bridged diuranium complex [{U(Ts-Tol)}(2)(mu-eta(6):eta(6)-C6H5-Me)] (3); combined structural, spectroscopic, magnetic, and computational analyses unambiguously confirm that the uranium centres in 3 are in the + 5 oxidation state and the toluene is a 10 pi-tetraanion.
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