期刊
DALTON TRANSACTIONS
卷 42, 期 8, 页码 2683-2686出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt32812g
关键词
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资金
- Ministry of Education, Culture, Science, Sports and Technology, Japan [20224015, 23350067, 22550053]
- Grants-in-Aid for Scientific Research [23750222, 23550076, 24655127, 23350067, 20224015, 22550053, 24108704] Funding Source: KAKEN
Linear Zn(II)-Ce(III)-Zn(II) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground F-2(5/2) state of Ce(III) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.
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