期刊
DALTON TRANSACTIONS
卷 42, 期 45, 页码 16102-16107出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51469b
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资金
- MEXT [17350085, 22108518, 24108726]
- Japan Society for the Promotion of Science (JSPS)
- Global COE Program of Osaka University
- JSPS
- Frontier Research Base for Global Young Researchers, Osaka University, on the Program of MEXT
- Ogasawara Foundation
- Asahi Grass Foundation
- Grants-in-Aid for Scientific Research [17350085, 22108518, 24108726] Funding Source: KAKEN
Hierarchical assemblies of the noteworthy photoactive cytochrome b562 reconstituted with zinc protoporphyrin IX covalently linked with the protein surface were constructed on a gold electrode modified with an apoprotein of cytochrome b562. The integrated photoactive hemoproteins were characterized by electrochemical impedance and quartz crystal microbalance analyses. The protein-immobilized electrode exhibits enhanced photocurrent generation relative to the one having a Zn-substituted hemoprotein monolayer.
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