期刊
DALTON TRANSACTIONS
卷 42, 期 44, 页码 15766-15773出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt52093e
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资金
- EPSRC
- Trinity College
- Clarendon Fund
Iodotriazole and triazole anion recognition groups have been integrated into a picket-fence zinc(II)-metalloporphyrin scaffold to produce receptors for anion recognition and sensing applications. H-1 NMR and UV/visible spectroscopic investigations reveal both host systems exhibit strong anion binding affinities in a range of solvent media. Importantly, the halogen-bonding iodotriazole-containing porphyrin-based host displays halide binding affinities substantially larger than the protic-functionalised analogue concomitant with a reduced strength of oxoanion complexation.
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