期刊
DALTON TRANSACTIONS
卷 42, 期 45, 页码 15906-15910出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51709h
关键词
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资金
- Evonik Foundation
- DFG [CL 489/2-1]
- FCI
Previously, we have reported on the quantitative self-assembly of a series of interpenetrated double-cages [Pd(4)Ligand(8)] with ligands based on various organic backbones. For dibenzosuber-one-based cages it was shown that anion binding in the outer two pockets follows an allosteric mechanism. Herein we wish to report the anion binding capabilities of three related phenothiazine cages. We present a systematic comparison of the relative halide (Cl- and Br-) binding affinities and the structural rearrangements of four double-cages based on NMR titrations, NOESY experiments and electronic structure calculations.
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