期刊
DALTON TRANSACTIONS
卷 42, 期 37, 页码 13335-13338出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3dt51414e
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资金
- Australia Research Council (ARC) through the ARC Future Fellowships program [FT100100344]
A new luminescent Zn-MOF has been synthesized under hydrothermal condition using a semi-rigid ligand H(3)pcoip (4-(2-carboxyphenoxy)isophthalic acid) is reported. The luminescence properties of 1 in methanol, ethanol, and water have been investigated. Interestingly, compound 1 has a unique response to methanol compared to ethanol and water. Moreover, 1 displays a turn-on switching property triggered by methanol solvent molecules and a high sensitivity towards methanol concentration as low as 2 x 10(-7) (V-MeOH/V-total) in ethanol solution. The results indicate that the Zn-MOF has potential application as a sensor for detecting methanol in ethanol solution with excellent selectivity and high sensitivity.
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