期刊
DALTON TRANSACTIONS
卷 41, 期 14, 页码 4164-4171出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12005d
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资金
- DFG [SPP 1362]
- European Community [228862]
A new family of Al-based MOFs denoted as CAU-3 (CAU = Christian-Albrechts-Universitat) was discovered in the solvothermal system Al3+/aryldicarboxylic acid/NaOH/methanol by applying high-throughput-methods. The three compounds reported in this article [Al-2(OCH3)(4)BDC], [Al-2(OCH3)(4)BDC-NH2] and[Al-2(OCH3)(4)NDC] (BDC = 1,4-benzenedicarboxylate; NDC = 2,6-naphtalenedicarboxylate) are all based on the same unprecedented inorganic building unit [Al-12(OCH3)(24)](12+), which is a dodecameric cyclic aluminium-methanolate-cluster. The material CAU-3-NDC was found to exhibit the highest surface area as well as the highest micropore volume of all Al-based MOFs reported until now.
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