期刊
DALTON TRANSACTIONS
卷 41, 期 14, 页码 3949-3952出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12300b
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资金
- European Research Council (ERC) [227781]
- European Research Council (ERC) [227781] Funding Source: European Research Council (ERC)
We report the mechanical properties of four isostructural metal-organic frameworks (MOFs) that adopt the ABX(3) perovskite topology: [(CH3)(2)NH2]M(HCOO)(3), where M = divalent Mn, Co, Ni, and Zn. Their Young's moduli were measured via single-crystal nanoindentation. We show that the mechanical stability of such isostructural frameworks with octahedral coordination increases with greater ligand field stabilization energy (LFSE).
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