期刊
DALTON TRANSACTIONS
卷 41, 期 30, 页码 9029-9032出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30926b
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资金
- Academy of Finland [139550]
- Academy of Finland (AKA) [139550, 139550] Funding Source: Academy of Finland (AKA)
Two 2-[bis(pentafluorophenyl)boryl]-N,N-dialkylanilines reported here exemplify a new class of intramolecular frustrated B/N Lewis pairs. A structure closely related to this class structure was synthesized in 2003 by Piers et al. but was unable to activate H-2. The new aminoboranes can activate hydrogen at near ambient conditions; besides, one of them can hydrogenate imines and enamines in a catalytic fashion demonstrating the validity of the original Piers' approach to hydrogen activation with ansa-aminoboranes.
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