期刊
DALTON TRANSACTIONS
卷 41, 期 25, 页码 7447-7453出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30105a
关键词
-
资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- Funding Program for Next Generation World-Leading Researchers [GR025]
- Toyota Motor Corporation
Quite recently we have found two nitrogen fixation systems catalyzed by molybdenum-dinitrogen complexes under mild reaction conditions; one is the transformation of molecular dinitrogen into its synthetic equivalent of ammonia and the other is that into ammonia. A molybdenum-dinitrogen complex bearing two ferrocenyl diphosphines works as a good catalyst in the transformation of molecular dinitrogen into silylamine, where up to 226 equiv are produced based on the catalyst. A dinitrogen-bridged dimolybdenum complex bearing a PNP-type pincer ligand works as a good catalyst in the direct transformation of molecular dinitrogen into ammonia, where up to 23 equiv are produced based on the catalyst. We believe that both systems provide a new aspect in the development of novel nitrogen fixation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据