期刊
DALTON TRANSACTIONS
卷 41, 期 46, 页码 14087-14100出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31728a
关键词
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资金
- Government of Spain [CTQ2009-11721]
- Junta de Andalucia [FQM6276]
- European Union (FEDER funds)
- Council of Grants of the President of the Russian Federation for young scientists [MK-966.2012.3]
Neophylpalladium complexes of the type [Pd(CH2CMe2Ph)(N-O)(L)], where N-O is picolinate or a related bidentate, monoanionic ligand (6-methylpyridine-2-carboxylate, quinoline-2-carboxylate, 2-pyridylacetate or pyridine-2-sulfonate) and L is pyridine or a pyridine derivative, efficiently catalyze the oxidation of a range of aliphatic, benzylic and allylic alcohols with oxygen, without requiring any additives. A versatile method is described which allows the synthesis of the above-mentioned complexes with a minimum synthetic effort from readily available materials. Comparison of the rates of oxidation of 1-phenylethanol with different catalysts reveals the influence of the structure of the bidentate N-O chelate and the monodentate ligand L on the catalytic performance of these complexes.
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