期刊
DALTON TRANSACTIONS
卷 41, 期 13, 页码 3740-3750出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12096h
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资金
- EU - Marie Curie Research and Training Network RevCat
- Dutch National School Combination Catalysis Controlled by Chemical Design (NRSC-Catalysis)
In this paper we report the application of bis-(thiosemicarbazonato) Zn(II) complexes as building blocks in the construction of supramolecular transition metal assemblies. We investigated their coordination behaviour towards pyridylphosphine molecules and found these systems comparable to those based on Zn(porphyrin) and Zn(salphen) complexes. Additionally, catalytic experiments and an in situ high-pressure FTIR study of the supramolecular rhodium hydroformylation catalysts, assembled using the bis-(thiosemicarbazonato) Zn(II) complexes, demonstrate their applicability in supramolecular catalysis and their potential for application in other areas of supramolecular chemistry.
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