期刊
DALTON TRANSACTIONS
卷 41, 期 25, 页码 7620-7623出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12296k
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资金
- Ministry of Education, Culture, Sports, Science and Technology [21244052]
We found that the alignments of the alkali cations can be controlled by a distortion of Prussian blue framework; the rubidium ions form a rod structure in a distorted framework of Rb0.85Cu-[Fe(CN)(6)](0.95)center dot 1.3H(2)O, while the cesium ions are isolated dot structures in a non-distorted framework of Cs0.97Cu[Fe(CN)(6)](0.99)center dot 1.1H(2)O. The Madelung energy calculations revealed that the novel rod structure is stabilized by the alternating rotations of the [Fe(CN)(6)] units within the three-dimensional coordination polymer framework.
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