期刊
DALTON TRANSACTIONS
卷 41, 期 44, 页码 13568-13571出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt31421e
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资金
- FCT (Portugal) [SFRH/BPD/74194/2010]
- FCT [PTDC/FIS/113500/2009]
- COST Action [CM1006 EUFEN]
- Fundação para a Ciência e a Tecnologia [SFRH/BPD/74194/2010] Funding Source: FCT
[U(Tp(Me2))(2)I] exhibits at low temperatures single molecule magnet (SMM) behaviour comparable to its bipyridine derivative and related single ion U(III) complexes recently reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in these compounds is well reproduced by quantum chemistry calculations.
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