期刊
DALTON TRANSACTIONS
卷 41, 期 13, 页码 3751-3757出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt11905f
关键词
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资金
- Australian Research Council
- Australian Institute of Nuclear Science and Engineering
- Australian Postgraduate Award scholarship
The nucleophilic addition of methanol and water to the dicyanonitrosomethanide anion, resulting in the formation of cyano(imino(methoxy)methyl)nitrosomethanide (cmnm) and carbamoylcyanonitrosomethanide (ccnm), respectively, is used as a means of in situ ligand synthesis during the formation of [Dy-8(OH)(6)(OMe)(6)(cmnm)(10)(ccnm)(2)(H2O)(2)(MeOH)(2)] (1). This is the first time these reactions have been observed to be promoted by the presence of a lanthanoid ion. The core of the octanuclear cluster consists of two cubane moieties ([Dy-4(OH)(3)(OMe)]), bridged by four methoxide ligands to form a central [Dy-8(OH)(6)(OMe)(6)] moiety. The complex displays magnetic properties that are indicative of probable single molecule magnet features.
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