期刊
DALTON TRANSACTIONS
卷 41, 期 4, 页码 1284-1288出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11765c
关键词
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资金
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2010-0010096]
- National Research Foundation of Korea [2010-0010096] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
The effect of the rutile content on the photovoltaic performance of dye-sensitized solar cells (DSSCs) composed of mixed-phase TiO2 photoelectrode has been investigated. The mixed-phase TiO2 particles with varied amounts of rutile, relative to anatase phase, are synthesized by an in situ method where the concentration of sulfate ion is used as a phase-controlling parameter in the formation of TiO2 using TiCl4 hydrolysis. The surface area (S-BET) varies from 33 (pure rutile) to 165 (pure anatase) m(2) g(-1). Generally, both the current density (J(sc)) and photo-conversion efficiency (eta) decrease as the rutile content increases. The incorporation of rod-shaped rutile particles causes low uptake of dye due to the reduced surface area, as well as slow electron transport in less efficiently-stacked structure. However, maximum J(sc) (14.63 mA cm(-2)) and eta (8.69%) appear when relatively low rutile content (16%) is employed. The reported synergistic effect by the efficient interparticle electron transport from rutile to anatase seems to overbalance the decrease of surface area when small amount of rutile particles is incorporated.
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