期刊
DALTON TRANSACTIONS
卷 41, 期 14, 页码 3953-3955出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt12088g
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资金
- Swedish Research Council (VR)
- Swedish Governmental Agency for Innovation Systems (VINNOVA) through the Berzelii Center EXSELENT
- Goran-Gustafsson Foundation for nature sciences and medical research
- Wenner Foundation
- Gren Foundation
A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.
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