期刊
DALTON TRANSACTIONS
卷 41, 期 33, 页码 9889-9892出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2dt30655g
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ESI-MS based methodology for the rapid reactivity screening of [PW11O39RhCl](5-) and [PW11O39Ir(H2O)](4-) toward various metalation-intended substrates (reagents with an activated C-H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh-R (R = malonate, phenylacetate, CH3, Ph, ferrocenyl) and Ir-R (R = CH3) bonds is reported.
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