期刊
DALTON TRANSACTIONS
卷 41, 期 14, 页码 3937-3941出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11729g
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资金
- EPSRC [EP/EO41825/1]
- European Commission [PIEF-GA-2009-236665]
- BBSRC
- University of Warwick through Birmingham Science City
- Advantage West Midlands (AWM)
- European Regional Development Fund (ERDF)
- EPSRC [EP/F017901/1, EP/E041825/1, EP/F018096/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F018096/1, EP/F017901/1, EP/E041825/1] Funding Source: researchfish
The scandium analogue of the flexible terephthalate MIL-53 yields a novel closed pore structure upon removal of guest molecules which has unusual thermal behaviour and stepwise opening during CO2 adsorption. By contrast, the nitro-functionalised MIL-53(Sc) cannot fully close and the structure possesses permanent porosity for CO2.
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