期刊
DALTON TRANSACTIONS
卷 40, 期 45, 页码 12056-12059出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt11225b
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资金
- Science Foundation Ireland (SFI)
- TCD
- Irish Research Council for Science, Engineering & Technology (IRCSET)
The reaction between the asymmetrical pyridyl ligands 3 (R) and 4 (S) and Eu(III) in CH3CN give rise to the formation of lanthanide luminescent 'half-helicates' in 1 : 3 (Ln:ligand) stoichiometry; the formation of which was observed by monitoring the changes in the ground and the excited state properties of the ligands, and in the time-resolved Eu-centred and the CPL emission.
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