期刊
DALTON TRANSACTIONS
卷 40, 期 35, 页码 9020-9025出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10287g
关键词
-
资金
- US National Science Foundation [CHE-0848248]
The addition of 2,6-dimethylphenyl isocyanide (CN[DMeP], two equivalents) to previously reported (PNP) Sc(III) pyridyl complexes resulted in the formation of novel indoline complexes of scandium. By varying the nature of the pyridyl moiety one can intercept an intermediate prior to methyl migration. In addition to structural studies of two indolene complexes, we also propose a mechanism for the insertion and indolene ring closure.
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