期刊
DALTON TRANSACTIONS
卷 40, 期 34, 页码 8533-8539出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1dt10547g
关键词
-
资金
- EC NoE MagMaNet
- EPSRC
- Institut Laue-Langevin
- Danish Natural Science Research Council (FNU) [09-062877]
- Royal Society
An investigation into the physical consequences of including a Jahn-Teller distorted Cu-II ion within an antiferromagnetically coupled ring, [R2NH2][Cr7CuF8(((O2CBu)-Bu-t)(16))] is reported. Inelastic neutron scattering (INS) and electron paramagnetic resonance (EPR) spectroscopic data are simulated using a microscopic spin Hamiltonian, and show that the two Cr-Cu exchange interactions must be inequivalent. One Cr-Cu exchange is found to be antiferromagnetic and the other ferromagnetic. The geometry of the Jahn-Teller elongation is deduced from these results, and shows that a Jahn-Teller elongation axis must lie in the plane of the Cr7Cu wheel; the elongation is not observed by X-ray crystallography, due to positional disorder of the Cu site within the wheel. An electronic structure calculation confirms the structural distortion of the Cu site.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据