期刊
DALTON TRANSACTIONS
卷 39, 期 7, 页码 1758-1762出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b917348j
关键词
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资金
- EPSRC
- U.S. Department of Energy [DE-AC02-05CH11231]
- Royal Society Wolfson Merit Award
- EPSRC [EP/F021925/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/F021925/1, EP/C006526/1] Funding Source: researchfish
Four zinc imidazolate materials has been synthesized under ionothermal conditions using ionic liquids; [Zn(C2O4)(C3N2H4)], P2(1)/a (1); [Zn(CH3COO)(C3N2H3)], Ima2 (2); [Zn-4(C3N2H4)(C3N2H3)(8)], P (1) over bar1 (3) and [Zn(C3N2H3)(2)], I4(1) (4). Compounds 1 and 4 have already known structures, but have been synthesised for the first time using ionothermal methods. Compounds 2 and 3 are novel and have been synthesized for the first time in this work. The syntheses of 3 and 4 take place under almost exactly the same conditions, except that a lower synthesis temperature leads to a proportion of terminal imidazolate units in the structure of 3 while a slightly higher temperature leads to all bridging imidazolate units in 4.
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