期刊
DALTON TRANSACTIONS
卷 39, 期 26, 页码 5949-5964出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b927026d
关键词
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资金
- U.S. Department of Energy, Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division and Division of Materials Sciences and Engineering [ER-15522]
In this Perspective we discuss a variety of methods that are broadly applicable to the syntheses of solid-state compounds. To illustrate the application of these methods we use solid-state actinide compounds, an area of chemistry that has been the focus of this laboratory for the last decade. We have synthesized single crystals, primarily of actinide chalcogenide compounds, by a variety of techniques. The benefits and drawbacks of each will be discussed in detail. Because of their propensity towards high coordination numbers and their ability to take on a variety of formal oxidation states, actinide compounds adopt structures illustrated here that are often different from those adopted by transition-metal or even lanthanide compounds. Often, there are corresponding differences in their physical properties, and these are touched upon here.
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