期刊
DALTON TRANSACTIONS
卷 39, 期 43, 页码 10382-10390出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00276c
关键词
-
资金
- EPSRC
- ERC
- EPSRC [EP/H015418/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish
The reaction of N, N '-bis(2,6-diisopropylphenyl) imidazol-2-ylidene gold hydroxide ([Au(OH)(IPr)]; 1) with acetylene and trimethylsilylacetylene derivatives cleanly leads to the formation of a gold-acetylide bond with the concomitant formation of water or trimethylsilanol. All compounds were isolated in high yield (> 85%). The crystal structures of selected gold acetylides in conjunction with their UV-vis absorption/emission properties were investigated. Finally, DFT calculations were performed in an attempt to gain an insight into the mechanism of the general reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据