期刊
DALTON TRANSACTIONS
卷 39, 期 33, 页码 7780-7785出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00140f
关键词
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资金
- Spanish Ministerio de Educacion y Ciencia [CTQ2006-084885/BQU, CSD2007-00006]
- FICYT of Asturias [IB08-036]
- MEC
- FICYT
The synthesis and characterization of chiral arene-ruthenium complexes [RuCl2(eta(6)-arene){(R)-PR-(binaphthoxy)}] (arene = benzene (1), p-cymene (2), mesitylene (3); R = Ph (a), OPh (b), piperidyl (c)) are described. Derivatives 1-3 have been employed to promote the kinetic resolution of allylic alcohols through a redox-isomerization process. As a general trend, the best selectivities are attained with the more sterically hindered catalysts i.e. those containing p-cymene or mesitylene ligands.
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