期刊
DALTON TRANSACTIONS
卷 39, 期 30, 页码 6950-6952出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00362j
关键词
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资金
- Army Research Office [W911NF- 09- 1-0426]
- UNC EFRC
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001011]
- U.S. Department of Energy [DE-SC0001298]
Electrocatalytic water oxidation occurs on high surface area, nanocrystalline ITO (nanoITO) surface-derivatized by phosphonate-binding of the catalyst [Ru(Mebimpy)-( 4,4 '-((HO)(2)OPCH(2))(2)bpy)(OH(2))](2+) (Mebimpy is 2,6-bis(1-methylbenzimidazol- 2-yl) pyridine; bpy is 2,2 '-bipyridine). With nanoITO, spectral data can be acquired on electrochemically generated intermediates and voltammograms monitored spectrophotometrically.
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