期刊
DALTON TRANSACTIONS
卷 39, 期 32, 页码 7440-7443出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0dt00485e
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资金
- Centre National de la Recherche Scientifique (CNRS)
A new heteroleptic gallium(III) complex, Ga6Cl6(mdea)(6) (1 2CHCl(3)) (mdeaH(2) = N-methyl diethanolamine) was prepared in good yield by a chloro-aminoalkoxo exchange reaction and used as a synthon for the synthesis of a novel group 13 heterometallic derivative, Ga2Al4(O)(2)(mdea)(2)(OPrt)(10) (2 2CHCl(3)), the latter acting as a facile single source precursor for the sol-gel preparation of the mixed Al-Ga oxide as a high surface area support for gold catalysts.
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