期刊
DALTON TRANSACTIONS
卷 -, 期 35, 页码 7223-7229出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b906730b
关键词
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资金
- MIUR [PRIN 2006038447, PRIN 20078EWK9B]
- Consolider-Ingenio 2010 [CSD2007-00006]
- Junta de Andalucia [FQM-3151]
Novel synthetic routes for the preparation of trinuclear copper(I) complexes with triscarbene ligands are presented, which yield higher purity products than the one previously described. The first crystal structure of one of these complexes is reported and confirms the expected structure. The trinuclear complexes proved to be efficient catalysts of Ullmann-type reactions as well as of the Sonogashira reaction.
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