期刊
DALTON TRANSACTIONS
卷 -, 期 41, 页码 8824-8827出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b908805a
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资金
- Dutch Polymer Institute, Eindhoven, the Netherlands [633]
- Ministero dell'Istruzione, dell'Universita e della Ricerca
A bis(phenoxy-amine)ZrMe2 complex (1) was synthesized and activated with B(C6F5)(3) obtaining an ion pair (2) having the MeB(C6F5)(3)(-) counterion in the second coordination sphere as deduced by NMR studies. Both DFT calculations and NMR investigations suggest that the activation is coupled with a change of the binding modality of the tetradentate ligand from cis(N,N)-trans(O,O) in the octahedral dimethyl precursor 1 to cis(N,N)-cis(O,O) in the ion pair 2.
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