期刊
CURRENT ORGANIC SYNTHESIS
卷 6, 期 3, 页码 290-324出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/157017909788921862
关键词
Allylic epoxides; nucleophilic ring opening; heteronucleophiles; carbon nucleophiles; regioselectivity; stereoselectivity; enantioselectivity
资金
- MIUR
- University of Pisa
- Merck Research Laboratories
Three-membered heterocyclic rings offer a powerful combination of reactivity, stability, availability, and atom economy. In fact, the asymmetric ring opening of allylic epoxides with nucleophiles of different kinds, as will be discussed in this Review, offers the possibility of generating valuable chiral non-racemic building blocks in a very simple manner and in a stereodefined fashion.
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