期刊
CURRENT ORGANIC CHEMISTRY
卷 18, 期 1, 页码 127-150出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/138527281801140121154544
关键词
Imine; Nucleophile; Asymmetric Organocatalysis; Dissymmetric BINOL; Chiral Bronsted Acids; Hydrogen-Bond; Enantiomeric Excess; Synthesis
资金
- Shanghai Saijia Chemicals Ltd., Shanghai Municipal Science and Technology Commission [12430501300]
Conformationally rigid phosphoric acids derived from suitably substituted axially dissymmetric 1,1'-bi-2,2'-naphthol (BI-NOL) find wide application in organic synthesis. These chiral Bronsted acids are able to catalyze enantioselective transformations of electrophilic imines with both carbon-centered and other hetero nucleophiles to generate enantioenriched products of academic, industrial and biological significance. Selected examples of this transformation as well as catalytic action and stereochemical features of plausible transition state intermediates are discussed in the present review.
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