期刊
CURRENT ORGANIC CHEMISTRY
卷 15, 期 13, 页码 2227-2256出版社
BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/138527211796150732
关键词
Bronsted acid; diels-alder reaction; enantioselectivity; ene reaction; friedel-crafts reaction; hydrogen bond; mannich reaction; organocatalysis
资金
- Ministry of Education, Culture, Sports, and Science and Technology, Japan
- Grants-in-Aid for Scientific Research [23655077] Funding Source: KAKEN
Chiral phosphoric acids derived from axially chiral biaryls and analogous chiral Bronsted acids have emerged as an attractive and widely applicable class of enantioselective organocatalysts for a variety of organic transformations. In this account article, we review our recent achievements and related works in the development of enantioselective carbon-carbon bond forming reactions using these axially chiral phosphoric acids and their analogues as chiral Bronsted acid catalysts. The contents are arranged according to the type of (pro) electrophiles, including imines, hemiaminal ethers, carbonyl compounds, and electron-rich double bonds, followed by specific reaction types. Further application to phosphoric acid/metal complex-combined catalytic systems is also highlighted.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据