期刊
CURRENT APPLIED PHYSICS
卷 10, 期 6, 页码 1422-1426出版社
ELSEVIER
DOI: 10.1016/j.cap.2010.05.007
关键词
Mesoporous materials; Co3O4; Electrochemical properties; Supercapacitor
资金
- National Natural Science Foundation of China [50772048]
- Natural Science Foundation of China Academy of Engineering Physics [10776014]
Mesoporous Co3O4 microspheres with unique crater-like morphology were obtained by utilizing the mesoporous silica material MCM-41 as a template. The analysis results of N-2 adsorption-desorption measurement indicate that the product has a large Brunauer-Emmett-Teller (BET) surface area of 60 m(2) g(-1) and a narrow pore size distribution centering around 3.7 nm. Its electrochemical properties were investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements. The findings reveal that this novel morphology material has a smaller inner resistance of about 0.4 Omega and a higher onset frequency of 550 Hz. This material can provide a high specific capacitance of 102 F g(-1) and a large capacity retention of 74% in 500 continuous cycles test at a sweep rate of 3 mV s(-1). More significantly, the mass loading of electroactive species can reach as large as 2 mg cm(-2), which is one order of magnitude larger than common amount used. (C) 2010 Elsevier B.V. All rights reserved.
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